- Title
- Stable five- and six-coordinate cobalt (III) complexes with a pentadentate bispidine ligand
- Creator
- Comba, Peter; Kerscher, Marion; Lawrance, Geoffrey Alan; Martin, Bodo; Wadepohl, Hubert; Wunderlich, Steffen
- Relation
- Angewandte Chemie-International Edition Vol. 47, Issue 25, p. 4740-4743
- Publisher Link
- http://dx.doi.org/10.1002/anie.200800515
- Publisher
- Wiley-VCH
- Resource Type
- journal article
- Date
- 2008
- Description
- I am ligand: A pentadentate bispidine ligand with two tertiary amine and three pyridine donors stabilizes the uncommon intermediate-spin electronic configuration of Co¹¹¹(S=1; see picture: C gray, N blue, O red, Co violet). Dissociation of the monodentate coligand yields a catalytically active pentacoordinate complex.
- Subject
- bispidines; cobalt; coordination chemistry; density functional; calculations; molecular mechanics
- Identifier
- http://hdl.handle.net/1959.13/43483
- Identifier
- uon:5582
- Identifier
- ISSN:1433-7851
- Language
- eng
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