Stable five- and six-coordinate cobalt (III) complexes with a pentadentate bispidine ligand

Title: Stable five- and six-coordinate cobalt (III) complexes with a pentadentate bispidine ligand
Creator: Comba, Peter; Kerscher, Marion; Lawrance, Geoffrey Alan; Martin, Bodo; Wadepohl, Hubert; Wunderlich, Steffen
Relation: Angewandte Chemie-International Edition Vol. 47, Issue 25, p. 4740-4743
Publisher Link: http://dx.doi.org/10.1002/anie.200800515
Publisher: Wiley-VCH
Resource Type: journal article
Date: 2008
Description: I am ligand: A pentadentate bispidine ligand with two tertiary amine and three pyridine donors stabilizes the uncommon intermediate-spin electronic configuration of Co¹¹¹(S=1; see picture: C gray, N blue, O red, Co violet). Dissociation of the monodentate coligand yields a catalytically active pentacoordinate complex.
Subject: bispidines; cobalt; coordination chemistry; density functional; calculations; molecular mechanics
Identifier: http://hdl.handle.net/1959.13/43483
Identifier: uon:5582
Identifier: ISSN:1433-7851
Language: eng
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