- Title
- Introducing a new heterogeneous nanocomposite thin film with superior mechanical properties and thermal stability
- Creator
- Zhao, Hong; Zheng, Zhong; Sun, Lixian; Liu, Hongwei; Tsoutas, Kostadinos; Akhavan, Behnam; Liu, Yanping; Bilek, Marcela M.; Liu, Zongwen
- Relation
- Materials & Design Vol. 234, Issue October 2023, no. 112333
- Publisher Link
- http://dx.doi.org/10.1016/j.matdes.2023.112333
- Publisher
- Elsevier
- Resource Type
- journal article
- Date
- 2023
- Description
- High entropy alloy (HEA) films offer excellent mechanical properties due to their random solid solution structure. However, their large grain boundary volume fraction can cause thermal instability, resulting in phase decomposition that affects their high-temperature performance. Nevertheless, it remains an interesting question whether phase decomposition can be used as a processing tool to create new HEA materials. In this study, AlCrFeCoNiCu0.5 HEA thin films were fabricated and annealed at 500 °C for up to 72 h. The 72-hour annealed thin film exhibited a 30 % increase in mechanical properties, exceeding most other HEA thin films. Characterization using X-ray and electron microscopy revealed a decomposition-induced phase transformation, which produced four new phases, including Cu-rich FCC phase, Cr-rich BCC phase, and ordered B2 phase of AlNi and FeCo. The enhanced mechanical properties were due to back stress strengthening and BCC + B2 phase strengthening. The 72-hour annealed thin film also showed excellent thermal stability through a new round of annealing, exhibiting a low variation in microstructure and chemical composition after being annealed at 500 °C for 100 h.
- Subject
- high entropy alloy thin films; heterogeneous nanocomposite; thermal stability; B2 phase; mechanical properties
- Identifier
- http://hdl.handle.net/1959.13/1492481
- Identifier
- uon:53354
- Identifier
- ISSN:0264-1275
- Rights
- © 2023 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
- Language
- eng
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