In Situ XAFS Study of a Modified TS-1 Framework for Carbonyl Formation

Title: In Situ XAFS Study of a Modified TS-1 Framework for Carbonyl Formation
Creator: Harvey, Luke; Kennedy, Eric; Stockenhuber, Michael
Relation: The Journal of Physical Chemistry C Vol. 125, Issue 30, p. 16483-16488
Publisher Link: http://dx.doi.org/10.1021/acs.jpcc.1c02348
Publisher: American Chemical Society
Resource Type: journal article
Date: 2021
Description: The in situ X-ray absorption fine structure (XAFS) was measured in the titanium-peroxo system supported by titanium silicalite-1 (TS-1). After this, the complex was heated, in line with previous in situ FTIR studies, in order to reproduce the catalytic conditions in those studies which demonstrate a reaction pathway to reaction products other than epoxides, namely, carbonyls, which have not been reported previously on this type of catalyst.
Subject: chemical structure; mathematical methods; oxides; titanium; X-ray absorption near edge spectroscopy
Identifier: http://hdl.handle.net/1959.13/1445238
Identifier: uon:42538
Identifier: ISSN:1932-7447
Language: eng
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