Kamlet-Taft solvation parameters of solvate ionic liquids

Title: Kamlet-Taft solvation parameters of solvate ionic liquids
Creator: Dolan, Andrew; Sherman, Dylan A.; Atkin, Rob; Warr, Gregory G.
Relation: ARC.DP130102298 http://purl.org/au-research/grants/arc/DP130102298
Relation: ChemPhysChem Vol. 17, Issue 19, p. 3096-3101
Publisher Link: http://dx.doi.org/10.1002/cphc.201600361
Publisher: Wiley- V C H Verlag GmbH & Co. KGaA
Resource Type: journal article
Date: 2016
Description: The Kamlet–Taft solvent parameters of solvate ionic liquids (SILs) prepared from lithium salts with glyme and glycol ligands are determined. The dipolarity/polarisibilities (π*) are high, similar to those found in conventional ionic liquids. The H-bond basicities (β) depend strongly on the anion. The H-bond acidities (α) are high in both glyme and glycol SILs, indicating that the lithium is acting as a H-bond donor site. “Poor” SILs have glyme-rich and salt-rich regions. In these liquids the π* and β values are almost identical to the parent glyme or glycol, and the α values are determined by the salt alone.
Subject: Kamlet–Taft solvent parameters; solvate ionic liquids (SILs); lithium salts; glyme; glycol ligands
Identifier: http://hdl.handle.net/1959.13/1347182
Identifier: uon:29990
Identifier: ISSN:1439-4235
Language: eng
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