- Title
- Changes in solvent-extracted matter for heated coal during metaplast formation using high-range mass spectrometry
- Creator
- Stanger, Rohan; Borrowdale, Josh; Smith, Nathan; Xei, Wei; Tran, Quang Anh; Lucas, John; Wall, Terry
- Relation
- ARC.DP140104185
- Relation
- Energy and Fuels Vol. 29, Issue 11, p. 7101-7113
- Publisher Link
- http://dx.doi.org/10.1021/acs.energyfuels.5b01850
- Publisher
- American Chemical Society
- Resource Type
- journal article
- Date
- 2015
- Description
- A fundamental study was undertaken to characterize the changes in solvent-extracted matter formed during the thermoplastic phase of coking. Coal samples were heated to fixed temperatures within the pyrolytic plastic range of 400-500 °C, and the volatile material was extracted in a two-stage extraction with acetone (light extract) and then tetrahydrofuran (THF heavy extract). The extracted material was analyzed using laser desorption ionization (time-of flight) mass spectrometry (LDI-TOF-MS). The LDI-TOF-MS results showed that three extracted fractions could be broadly classified here as overlapping molecular weight ranges as volatile tars (200-450 Da), light acetone-soluble extract (250-500 Da), and heavy THF-soluble extract (300-1200 Da). A further class of compounds was identified from THF extraction of the raw coal in the range of 600-2500 Da that required higher laser powers to ionize and was not observed in the thermally generated samples. Negligible changes were observed in the composition of the acetone-soluble extracts with temperature, while the THF-soluble extract showed smaller proportions of larger molecules with higher treatment temperatures. It was observed that each molecular weight spectrum showed repeating structural units forming peaks every 12-14 Da (homologous series), with distributions of species around each peak. The volatile tar and acetone-soluble material shared common repeating structures also evident in the raw coal extract. This suggested that the material in this fraction was thermally stable over the analyzed temperature range. The repeating features of the THF-soluble extract species appeared to be structurally different. Overall, this work has indicated that development of extractable matter expected to be associated with fluidity during coking and subsequent resolidification relies on <1000 Da compounds. The results showed that >600 Da compounds are thermally sensitive. Compounds with molecular weights of <450 Da may be removed during coking, possibly as a vapor, resulting in a reduction in fluidity. There has been speculation that the thermally stable (acetone-soluble) material identified in both raw coal extract and those from thermally treated samples may be capable of undergoing a phase change to initiate plastic deformation.
- Subject
- solvent extracted matter; coking coals; pyrolitic plastic range; softening coal structure
- Identifier
- http://hdl.handle.net/1959.13/1329541
- Identifier
- uon:26187
- Identifier
- ISSN:0887-0624
- Language
- eng
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