- Title
- Partial oxidation of methane with nitrous oxide forms synthesis gas over cobalt exchanged ZSM-5
- Creator
- Khan, Naseer A.; Kennedy, Eric M.; Dlugogorski, Bogdan Z.; Adesina, Adesoji A.; Stockenhuber, Michael
- Relation
- Catalysis Communications Vol. 53, p. 42-46
- Publisher Link
- http://dx.doi.org/10.1016/j.catcom.2014.04.012
- Publisher
- Elsevier BV
- Resource Type
- journal article
- Date
- 2014
- Description
- Synthesis gas (CO + H₂) is a versatile and significant resource. In this communication we show that cobalt loaded on ZSM-5 (Co-ZSM-5) catalyses the formation of synthesis gas from CH₄, under partial oxidation conditions using N₂O as oxidant. With O₂ as oxidant over the same Co-ZSM-5 catalyst, cobalt on alumina and Fe-ZSM-5, only COₓ and H₂O are formed. Isolated Co²⁺ sites in the ZSM-5 support are proposed as the active sites for H₂ (synthesis gas) formation.
- Subject
- Co-ZSM-5; partial oxidation; N₂O; CH₄
- Identifier
- http://hdl.handle.net/1959.13/1302989
- Identifier
- uon:20583
- Identifier
- ISSN:1566-7367
- Language
- eng
- Reviewed
- Hits: 1909
- Visitors: 2141
- Downloads: 0
Thumbnail | File | Description | Size | Format |
---|