- Title
- Interactions between halide anions and interfacial water molecules in relation to the Jones-Ray effect
- Creator
- Nguyen, Khoi Tan; Nguyen, Anh V.; Evans, Geoffrey M.
- Relation
- Australian Research Council.LE0989675 and DP1401089
- Relation
- Physical Chemistry Chemical Physics Vol. 16, Issue 45, p. 24661-24665
- Publisher Link
- http://dx.doi.org/10.1039/c4cp03629h
- Publisher
- RSC Publications
- Resource Type
- journal article
- Date
- 2014
- Description
- The Jones–Ray effect is shown to be governed by a different mechanism to enhanced anion adsorption. Halide ions at sub-molar concentrations are not exposed to the vapour phase; instead their first-solvating shell intimately interacts with the outmost water layer. Our novel proposal opens challenges for predicting related interfacial phenomena consistently.
- Subject
- halide anions; anion adsorption; vapour phase; water; molecules
- Identifier
- http://hdl.handle.net/1959.13/1061777
- Identifier
- uon:17008
- Identifier
- ISSN:1463-9076
- Language
- eng
- Full Text
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