Determining the orientation of a chiral substrate using full-hemisphere angle-resolved photoelectron spectroscopy

Title: Determining the orientation of a chiral substrate using full-hemisphere angle-resolved photoelectron spectroscopy
Creator: Tadich, A.; Riley, J.; Thomsen, L.; Cowie, B. C. C.; Gladys, M. J.
Relation: Physical Review Letters Vol. 107, Issue 17, p. 175501-1-175501-4
Publisher Link: http://dx.doi.org/10.1103/PhysRevLett.107.175501
Publisher: American Physical Society
Resource Type: journal article
Date: 2011
Description: Chiral interfaces and substrates are of increasing importance in the field of enantioselective chemistry. To fully understand the enantiospecific interactions between chiral adsorbate molecules and the chiral substrate, it is vital that the chiral orientation of the substrate is known. In this Letter we demonstrate that full-hemisphere angle-resolved photoemission permits straightforward identification of the orientation of a chiral surface. The technique can be applied to any solid state system for which photoemission measurements are possible.
Subject: chiral interfaces; substrates; enantioselective chemistry; absorbate; photoemission
Identifier: http://hdl.handle.net/1959.13/1059518
Identifier: uon:16628
Identifier: ISSN:0031-9007
Language: eng
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