- Title
- Electrochemical impedance spectroscopy study into the effect of titanium dioxide added to the alkaline manganese dioxide cathode
- Creator
- Bailey, Mark R.; Donne, Scott W.
- Relation
- Journal of the Electrochemical Society Vol. 158, Issue 7, p. A802-A808
- Publisher Link
- http://dx.doi.org/10.1149/1.3586045
- Publisher
- Electrochemical Society
- Resource Type
- journal article
- Date
- 2011
- Description
- A combination of step potential electrochemical spectroscopy (SPECS) and electrochemical impedance spectroscopy (EIS) has been used to examine the effect of anatase titanium dioxide added to the alkaline manganese dioxide electrode. The inclusion of titanium dioxide was found to improve performance by lowering the resistance to charge transfer at the MnO2/electrolyte/graphite interface. Furthermore, a consideration of mass transport processes within the electrode indicates that titanium ions may become incorporated into the γ-MnO2 lattice upon cycling, impacting H+/e− mass transport.
- Subject
- charge exchange; electrochemical electrodes; electrochemical impedance spectroscopy; electrolytes
- Identifier
- http://hdl.handle.net/1959.13/1053653
- Identifier
- uon:15645
- Identifier
- ISSN:0013-4651
- Rights
- © The Electrochemical Society, Inc. 2011. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version of this work was published in Journal of the Electrochemical Society Vol. 158, No. 7, pp. A802-808.
- Language
- eng
- Full Text
- Reviewed
- Hits: 998
- Visitors: 1286
- Downloads: 324
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | ATTACHMENT01 | Publisher version (open access) | 1 MB | Adobe Acrobat PDF | View Details Download |