Conjoint analysis of kinetic and equilibrium data for mechanistic elucidation in polynuclear complexation reactions, exemplified by metal(II) helicate complex formation

Title: Conjoint analysis of kinetic and equilibrium data for mechanistic elucidation in polynuclear complexation reactions, exemplified by metal(II) helicate complex formation
Creator: Clifford, Sarah E.; Lawrance, Geoffrey A.; Neuhold, Yorck-Michael; Maeder, Marcel
Relation: Australian Journal of Chemistry Vol. 63, Issue 1, p. 141-144
Publisher Link: http://dx.doi.org/10.1071/ch09316
Publisher: CSIRO Publishing
Resource Type: journal article
Date: 2010
Description: Combined kinetic and equilibrium studies of the complexation of the ligand N,N′-bis[2-(2-pyridyl)methyl]pyridine-2,6-dicarboxamide with copper(ii) and nickel(ii), examined conjointly employing advanced chemometric methods, provides elucidation of speciation and formation pathways in solution for complexes such as M₂L₂ and M₂L₃ helicates, respectively.
Subject: complexation; ligand; chemometric methods; helicates
Identifier: http://hdl.handle.net/1959.13/931763
Identifier: uon:11161
Identifier: ISSN:0004-9425
Language: eng
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