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Title
Hydrothermal MnO2: synthesis, structure, morphology and discharge performance
Author/Creator
Walanda, David Karel;  Lawrance, Geoffrey A.;  Donne, Scott W.
Description
Digestion of Mn2O3 in a range of H2SO4 solutions (0.01-0 M), at a variety of temperatures (20-140degreesC) has led to the formation of a series of kinetically stable manganese dioxide samples via a dissolution-precipitation mechanism that involves disproportionation of a soluble Mn(Ill) intermediate. The resultant manganese dioxide samples are characterized in terms of their domain of phase stability, chemical composition, structure, morphology and electrochemical performance. gamma-MnO2 predominates at all but high H2SO4 concentrations (>5 M), where alpha-MnO2 is formed, and high temperatures (>80degreesC) where beta-MnO2 is formed. The structural variety of gamma-MnO2 in this domain of stability is interpreted in terms of: (i) the fraction of De Wolff defects (P,), which is found to increase as the H2SO4 concentration is decreased and the temperature is increased; (ii) microtwinning (T-w), which despite being less statistically significant, is found to follow a similar trend; (iii) the cation vacancy fraction; (iv) the Mn(III) fraction. Both the latter structural properties decrease as the temperature is increased; but decreasing the H2SO4 concentration leads to a decrease in cation vacancy fraction and an increase in Mn(III) fraction. These structural characteristics, in particular the De Wolff defects, are interpreted on a molecular level in terms of soluble Mn(III) intermediate condensation, in which the electrolyte conditions determine the relative proportions of equatorial-axial edge sharing (ramsdellite domains only), and equatorial-axial corner sharing (both ramsdellite and pyrolusite domains) that occurs. Morphological differentiation is easily established due to the different characteristics of each phase. gamma-MnO2 exists as fine needles (250 nm x 50 nm), beta-MnO2 is formed as much larger columns (1 mum x 100 nm), while alpha-MnO2 is present as small spheres of up to 400 nm in diameter. Electrochemical characterization by voltammetry in an aqueous 9 M KOH electrolyte demonstrates that the performance of gamma-MnO2 Samples is comparable with that of commercial EMD, whereas alpha- and beta-MnO2 suffer from diffusional limitations which lower their operating voltage. For gamma-MnO2, superior performance results when lower temperatures and H2SO4 concentrations are used. This corresponds to intermediate levels of De Wolff defects and microtwinning, and to a cation vacancy fraction minimum.
Relation
Journal of Power Sources Vol. 139, no. 1-2, p. 325-341
Date
2005
Publisher
Elsevier Sequoia
Keyword(s)
manganese dioxide;  hydrothermal synthesis;  phase diagram;  electrochemical performance;  manganese-dioxide electrode;  cathodic reduction mechanism;  alkaline;  electrolyte;  redox processes;  phase transformation;  sulfuric acid;  gamma EMD;  digestion;  system
Resource Type
journal article
Identifier
http://hdl.handle.net/1959.13/24532
Identifier
ISSN:0378-7753
Language
eng
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Subject
"Journal of Power Sources"
 
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