Please use this identifier to cite or link to this item: http://hdl.handle.net/1959.13/802939
- Title
- Field ionization detection for atom microscopy
- Author/Creator
-
O'Donnell, Kane
- Institution
- University of Newcastle. Faculty of Science and Information Technology, School of Mathematical and Physical Sciences
- Description
- Research Doctorate - Doctor of Philosophy (PhD)
- Description
- Helium has the highest ionization energy of any species and is as a consequence difficult to detect by conventional means. On the other hand, it is the ideal surface probe, having no net charge or spin, a low mass and a short de Broglie wavelength. Therefore, there exists a strong incentive to develop a microscopy technique based on helium atom scattering. The purpose of this thesis is to investigate in detail how an efficient helium detector might be developed using the phenomenon of field ionization, an ionization method that relies on quantum mechanical tunneling rather than the more conventional electron impact ionization techniques. In particular, the work focusses on the potential use of a novel nanomaterial, carbon nanotubes, as the source of the high electric fields required for field ionization detection. In Chapter 1 we review the history of field ionization research and the properties and synthesis methods for carbon nanotubes. Chapter 2 describes the experimental apparatus and procedures used for the present research, and Chapter 3 introduces the theoretical framework and background for field ionization. In Chapter 4, the prototypical field ionization system is considered from a detector viewpoint. The work demonstrates that existing theory is not sufficiently quantitative for describing a field ionization detector and therefore a semi-empirical theory is advanced for that purpose. Chapter 5 considers the problem of nanotube field enhancement in detail using computational methods, leading to a complete description of the maximum field enhancement of a nanotube array based on the four fundamental array parameters. Efforts to synthesize carbon nanotubes in the Newcastle plasma-enhanced chemical vapor deposition system are described in Chapter 6. Several procedures are developed for reproducible growth of nanotube films and the chemical vapor deposition system is characterized with single parameter studies. Chapter 7 presents the results of electron field emission and helium field ionization experiments carried out using the grown nanotube films. We demonstrate for the first time the field ionization of helium using a planar film of carbon nanotubes. Finally, we conclude the investigation of field ionization detection in Chapter 8 with a discussion on how such a detection method integrates into a helium microscope and in particular we detail the design and initial calculations for the planned Newcastle helium microscope.
- Relation
- University of Newcastle Research Higher Degree Thesis
- Date
- 2010
- Keyword(s)
-
field-ionization;
field-ionisation;
helium-beam;
carbon-nanotubes;
atom-microscope;
atom-microscopy;
chemical-vapor-deposition;
helium;
helium-atom-microscopy;
helium-microscopy;
free-jet-expansion
- Resource Type
- thesis
- Rights
- Copyright 2010 Kane O'Donnell
- Identifier
- http://hdl.handle.net/1959.13/802939
- Language
- eng
- Full Text
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