Stable five- and six-coordinate cobalt (III) complexes with a pentadentate bispidine ligand | NOVA. The University of Newcastle's Digital Repository

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Please use this identifier to cite or link to this item: http://hdl.handle.net/1959.13/43483

Title: Stable five- and six-coordinate cobalt (III) complexes with a pentadentate bispidine ligand
Author/Creator: Comba, Peter; Kerscher, Marion; Lawrance, Geoffrey Alan; Martin, Bodo; Wadepohl, Hubert; Wunderlich, Steffen
Institution: The University of Newcastle. Faculty of Science & Information Technology, School of Environmental and Life Sciences
Description: I am ligand: A pentadentate bispidine ligand with two tertiary amine and three pyridine donors stabilizes the uncommon intermediate-spin electronic configuration of Co¹¹¹(S=1; see picture: C gray, N blue, O red, Co violet). Dissociation of the monodentate coligand yields a catalytically active pentacoordinate complex.
Relation: Angewandte Chemie-International Edition Vol. 47, Issue 25, p. 4740-4743
Publisher Link: http://dx.doi.org/10.1002/anie.200800515
Date: 2008
Publisher: Wiley-VCH
Keyword(s): bispidines; cobalt; coordination chemistry; density functional; calculations; molecular mechanics
Resource Type: journal article
Identifier: http://hdl.handle.net/1959.13/43483
Identifier: ISSN:1433-7851

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